Co(II) and Cd(II) Complexes Based on 5-[(2-Methyl-1H-imidazol-1-yl)methyl]isophthalate: Syntheses, Characterization and Properties
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چکیده
Co(II) nitrate reacts with potassium 5-[(2-methyl-1H-imidazol-1-yl)methyl]isophthalate (K2L) under hydrothermal conditions to yield a new complex [Co(L)(H2O)] (1). In the presence of 2-(pyridin2-yl)-1H-benzo[d]imidazole (pybim) as auxiliary ligand, complex [Cd(L)(pybim)] (2) can be obtained using Cd(NO3)2. Complexes 1 and 2 have been characterized by single-crystal and powder X-ray diffraction, IR, elemental and thermogravimetric analyses. Complex 1 exhibits a 2-fold interpenetrated 3D framework architecture with (10,3)-a topology; complex 2 consists of a 2D fes network with (4.82) topology. The fluorescence properties of 2 were also investigated.
منابع مشابه
Syntheses, Structures and Properties of Two Cd(II) Complexes Based on the 2-(1H-Imidazol-1-yl-methyl)-1H-benzimidazole Ligand
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تاریخ انتشار 2013